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Issue 45, 2019
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Complete post-synthetic modification of a spin crossover complex

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Abstract

The post-synthetic reaction between p-anisaldehyde and the spin-crossover compound [Fe(NH2-trz)3](NO3)2 was explored, obtaining different degrees of transformation from 23% to full conversion by varying the reaction time. The post-synthetic SCO complexes obtained were studied by magnetometry, powder X-ray diffraction (PXRD), elemental analysis, solid state NMR and IR and compared with the corresponding compounds obtained by direct synthetic routes, revealing new spin crossover properties.

Graphical abstract: Complete post-synthetic modification of a spin crossover complex

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Publication details

The article was received on 05 Sep 2019, accepted on 22 Oct 2019 and first published on 23 Oct 2019


Article type: Communication
DOI: 10.1039/C9DT03587G
Dalton Trans., 2019,48, 16853-16856

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    Complete post-synthetic modification of a spin crossover complex

    A. Enríquez-Cabrera, L. Routaboul, L. Salmon and A. Bousseksou, Dalton Trans., 2019, 48, 16853
    DOI: 10.1039/C9DT03587G

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