Issue 45, 2019
From the journal:

Dalton Transactions

An unprecedented [{Fe5O5(OH)2(OAc)2}2{W2O2(OH)}] cluster sandwiched in the tetravacant tungstophosphate†

Zongfei Yang,a   Yaping Wang,a   Zhijie Liang,a   Jingkun Lu,a   Pengtao Ma, ORCID logo a   Jingyang Niu ORCID logo *a  and  Jingping Wang ORCID logo *a  

* Corresponding authors

a Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, P. R. China
E-mail: jyniu@henu.edu.cn, jpwang@henu.edu.cn
Fax: (+86)371-23886876

Abstract

A novel tungstophosphate H12Na4K3[{Fe5O5(OH)2(OAc)2}2{W2-O2(OH)}{P2W14O54}2]·36H2O (1) containing an unprecedented [{Fe5O5(OH)2(OAc)2}2{W2O2(OH)}] unit has been successfully obtained and characterized by IR, TGA, magnetic susceptibility measurements and single-crystal X-ray diffraction. It shows a decameric FeIII molecular assembly formed through two {Fe5O23} subunits bridged by a {W2O3} motif.

Graphical abstract: An unprecedented [{Fe5O5(OH)2(OAc)2}2{W2O2(OH)}] cluster sandwiched in the tetravacant tungstophosphate

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Article information

DOI
https://doi.org/10.1039/C9DT03524A
Article type
Communication
Submitted
02 Sep 2019
Accepted
29 Oct 2019
First published
29 Oct 2019

Dalton Trans., 2019,48, 16857-16860

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An unprecedented [{Fe5O5(OH)2(OAc)2}2{W2O2(OH)}] cluster sandwiched in the tetravacant tungstophosphate

Z. Yang, Y. Wang, Z. Liang, J. Lu, P. Ma, J. Niu and J. Wang, Dalton Trans., 2019, 48, 16857 DOI: 10.1039/C9DT03524A

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