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Decanuclear FeIII clusters with hemiacetal ligands: a new {M103-O)8} cluster core

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Abstract

The characterization of a decanuclear FeIII cluster with α-methyl-2-pyridinemethanolate, generated by the hydrolysis of Schiff bases, inspired us to carry out an initial exploration of the direct syntheses of medium nuclearity FeIII clusters starting from aldehydes in methanolic medium. The new complexes exhibit an unprecedented {Fe103-O)8} cluster core.

Graphical abstract: Decanuclear FeIII clusters with hemiacetal ligands: a new {M10(μ3-O)8} cluster core

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Publication details

The article was received on 12 Apr 2019, accepted on 01 Jul 2019 and first published on 01 Jul 2019


Article type: Communication
DOI: 10.1039/C9DT01568J
Dalton Trans., 2019, Advance Article

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    Decanuclear FeIII clusters with hemiacetal ligands: a new {M103-O)8} cluster core

    J. Mayans, L. Roc, M. Font-Bardia and A. Escuer, Dalton Trans., 2019, Advance Article , DOI: 10.1039/C9DT01568J

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