Issue 22, 2019
From the journal:

Dalton Transactions

MX-type single chain complexes with an aromatic in-plane ligand: incorporation of aromatic interactions for stabilizing the chain structure†

Unjila Afrin,a   Hiroaki Iguchi, ORCID logo *a   Mohammad Rasel Mian,a   Shinya Takaishi, ORCID logo a   Hiromichi Yamakawa,b   Tsubasa Terashige,c   Tatsuya Miyamoto,b   Hiroshi Okamotobc  and  Masahiro Yamashita*ade  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Aoba-ku, Sendai 980-8578, Japan
E-mail: h-iguchi@m.tohoku.ac.jp, yamasita@agnus.chem.tohoku.ac.jp

b Department of Advanced Material Science, Graduate School of Frontier Sciences, The University of Tokyo, Kashiwa 277-8561, Japan

c AIST-UTokyo Advanced Operando-Measurement Technology Open Innovation Laboratory, National Institute of Advanced Industrial Science and Technology, Chiba 277-8568, Japan

d Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-Ku, Sendai 980-8577, Japan

e School of Materials Science and Engineering, Nankai University, Tianjin 300350, China

Abstract

MX-type one-dimensional complexes [PtIV(amp)2Br2][PtII/IV(amp)2Br]2(HSO4)2(SO4)2·13H2O (3) and [PtIV(amp)2Br2][PtII/IV(amp)2Br]2(H2PO4)6·8H2O (4) were synthesized as the first analogue containing only an aromatic in-plane ligand. The Pt–Br chain structures of 3 and 4 are stabilized by both the hydrogen-bond network along the chain and the π-stacking via intercalated Pt(IV) complexes. Structural and spectroscopic studies indicated that both 3 and 4 form the Pt(II/IV) mixed valence state.

Graphical abstract: MX-type single chain complexes with an aromatic in-plane ligand: incorporation of aromatic interactions for stabilizing the chain structure

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Article information

DOI
https://doi.org/10.1039/C9DT00784A
Article type
Paper
Submitted
21 Feb 2019
Accepted
24 Apr 2019
First published
24 Apr 2019

Dalton Trans., 2019,48, 7828-7834

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MX-type single chain complexes with an aromatic in-plane ligand: incorporation of aromatic interactions for stabilizing the chain structure

U. Afrin, H. Iguchi, M. R. Mian, S. Takaishi, H. Yamakawa, T. Terashige, T. Miyamoto, H. Okamoto and M. Yamashita, Dalton Trans., 2019, 48, 7828 DOI: 10.1039/C9DT00784A

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