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Metastable phosphorus neutral monoradical: a key intermediate in the bicyclic cage formation

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Abstract

A key intermediate in the formation of a bicyclic cage formed between a biradical (LCP)2 (L = carbene) and an unsaturated substrate via a [2 + 2] cycloaddition reaction has been isolated and fully characterized including by X-ray diffraction analysis. The isolation of this intermediate proves that this cycloaddition reaction proceeds stepwise which is preferred over a concerted mechanism.

Graphical abstract: Metastable phosphorus neutral monoradical: a key intermediate in the bicyclic cage formation

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Publication details

The article was received on 07 Dec 2018, accepted on 14 Jan 2019 and first published on 15 Jan 2019


Article type: Communication
DOI: 10.1039/C8DT04842H
Citation: Dalton Trans., 2019, Advance Article

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    Metastable phosphorus neutral monoradical: a key intermediate in the bicyclic cage formation

    X. Chen, A. Hinz, J. R. Harmer and Z. Li, Dalton Trans., 2019, Advance Article , DOI: 10.1039/C8DT04842H

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