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Combining two distinctive intermolecular forces in designing ternary co-crystals and molecular salts of 1,3,5-trinitrobenzene, 9-anthracenecarboxylic acid and ten substituted pyridines

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Abstract

A series of ten ternary complexes, consisting of a charge transfer binary complex hydrogen bonded to a third component, are synthesized using neutral and charge-assisted hydrogen bonding. The colours of the ternary complexes change from yellow to orange to red depending on the identity of the third component, being a number of pyridines with nitro, amino or halogen atom substituents.

Graphical abstract: Combining two distinctive intermolecular forces in designing ternary co-crystals and molecular salts of 1,3,5-trinitrobenzene, 9-anthracenecarboxylic acid and ten substituted pyridines

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Publication details

The article was received on 18 Jan 2019, accepted on 07 Aug 2019 and first published on 08 Aug 2019


Article type: Communication
DOI: 10.1039/C9CE00093C
CrystEngComm, 2019, Advance Article

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    Combining two distinctive intermolecular forces in designing ternary co-crystals and molecular salts of 1,3,5-trinitrobenzene, 9-anthracenecarboxylic acid and ten substituted pyridines

    T. Hill, R. M. Erasmus, D. C. Levendis and A. Lemmerer, CrystEngComm, 2019, Advance Article , DOI: 10.1039/C9CE00093C

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