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The Fischer–Tropsch reaction in the aqueous phase over rhodium catalysts: a promising route to selective synthesis and separation of oxygenates and hydrocarbons

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Abstract

In the present communication, we uncovered the aqueous phase Fischer–Tropsch reaction over rhodium catalysts. The reaction results in the synthesis and consecutive separation of hydrocarbons and oxygenates into two phases. Use of a rhodium Schiff base complex as a precursor for catalyst preparation allows efficient control of the Rh metal nanoparticle size distribution and leads to higher alcohol selectivity.

Graphical abstract: The Fischer–Tropsch reaction in the aqueous phase over rhodium catalysts: a promising route to selective synthesis and separation of oxygenates and hydrocarbons

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The article was received on 19 Nov 2019, accepted on 26 Nov 2019 and first published on 26 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC09026F
Chem. Commun., 2020, Advance Article

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    The Fischer–Tropsch reaction in the aqueous phase over rhodium catalysts: a promising route to selective synthesis and separation of oxygenates and hydrocarbons

    A. S. Peregudova, A. J. Barrios, V. V. Ordomsky, N. E. Borisova and A. Y. Khodakov, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC09026F

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