Issue 97, 2019
From the journal:

Chemical Communications

Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom†

Mahendra K. Sharma, ORCID logo a   Beate Neumann,a   Hans-Georg Stammler,a   Diego M. Andradab  and  Rajendra S. Ghadwal ORCID logo *a  

* Corresponding authors

a Anorganische Molekülchemie und Katalyse, Lehrstuhl für Anorganische Chemie und Strukturchemie, Centrum für Molekulare Materialien, Fakultät für Chemie, Universität Bielefeld, Universitätsstr. 25, D-33615 Bielefeld, Germany
E-mail: rghadwal@uni-bielefeld.de
Web: http://www.ghadwalgroup.de
Fax: +49 521 106 6026
Tel: +46 521 106 6167

b Allgemeine und Anorganische Chemie, Universität des Saarlandes, Campus C4.1, D-66123 Saarbrücken, Germany

Abstract

The first terminal arsinidene complexes [{(NHC)C(Ph)}As]Fe(CO)4 (NHC = IPr = C{(NDipp)CH}25, Me-IPr = C{(NDipp)CMe}26; Dipp = 2,6-iPr2C6H3) with a two-coordinated arsenic atom have been reported as crystalline solids. Calculations suggest that 5 and 6 are electrophilic, which has been demonstrated by the reaction of 5 with an NHC nucleophile (IMe4), affording the Lewis adduct [{(IPr)C(Ph)}As(IMe4)]Fe(CO)4 (7) (IMe4 = C(NMeCMe)2).

Graphical abstract: Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C9CC08630G
Article type
Communication
Submitted
05 Nov 2019
Accepted
08 Nov 2019
First published
11 Nov 2019

Chem. Commun., 2019,55, 14669-14672

Permissions

Request permissions

Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom

M. K. Sharma, B. Neumann, H. Stammler, D. M. Andrada and R. S. Ghadwal, Chem. Commun., 2019, 55, 14669 DOI: 10.1039/C9CC08630G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements