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Issue 98, 2019
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Ba4(BS3S)2S4: a new thioborate with unprecedented [BS3-S] and [S4] fundamental building blocks

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Abstract

Ba4(BS3S)2S4 with unprecedented [BS3-S] and [S4] units has been synthesized successfully. The [BS3-S] unit named as (disulfido)bis(sulfido)borate(3-) is composed of a planar [BS3] group with a non-polar covalent S–S bond and stabilized by a large π-conjugation structure. The [S4] unit, formed by four S atoms, shows a helix chain-like structure. This work will enrich the structural diversity of boron chemistry.

Graphical abstract: Ba4(BS3S)2S4: a new thioborate with unprecedented [BS3-S] and [S4] fundamental building blocks

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Publication details

The article was received on 09 Oct 2019, accepted on 14 Nov 2019 and first published on 14 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC07930K
Chem. Commun., 2019,55, 14793-14796

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    Ba4(BS3S)2S4: a new thioborate with unprecedented [BS3-S] and [S4] fundamental building blocks

    G. Li, J. Li, K. Wu, Z. Yang and S. Pan, Chem. Commun., 2019, 55, 14793
    DOI: 10.1039/C9CC07930K

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