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Reversible multi-electron storage in dual-site redox-active supramolecular cages

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Abstract

M6L412+ supramolecular cages 3a and 3b (M = Pd, Pt), soluble in organic solvents, contain two different ligand-centered redox sites that enable the reversible storage of up to 16 electrons, as probed by CV, UV/vis spectro-electrochemistry (SEC-UV/Vis), bulk electrolysis and EPR. Encapsulation of a B12F122− anion is confirmed by 1H, 19F NMR and 19F DOSY NMR spectroscopy and mass spectrometry.

Graphical abstract: Reversible multi-electron storage in dual-site redox-active supramolecular cages

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Publication details

The article was received on 12 Sep 2019, accepted on 27 Sep 2019 and first published on 28 Sep 2019


Article type: Communication
DOI: 10.1039/C9CC07138E
Chem. Commun., 2019, Advance Article

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    Reversible multi-electron storage in dual-site redox-active supramolecular cages

    R. Plessius, N. Orth, I. Ivanović-Burmazović, M. A. Siegler, J. N. H. Reek and J. I. van der Vlugt, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC07138E

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