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Catalyst-free phosphorylation of aryl halides with trialkyl phosphites through electrochemical reduction

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Abstract

A catalyst-free electrochemical cross-coupling reaction of aryl halides with trialkyl phosphite has been developed. This reaction proceeds in an undivided cell with a low-cost Ni anode and a graphite cathode under mild and neutral conditions. A wide range of functional groups are well-tolerated and the phosphorylated product can be obtained on the gram scale, showing that this transformation has the potential to be a valuable method for the construction of aromatic carbon–phosphorus bonds.

Graphical abstract: Catalyst-free phosphorylation of aryl halides with trialkyl phosphites through electrochemical reduction

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Publication details

The article was received on 10 Sep 2019, accepted on 28 Oct 2019 and first published on 29 Oct 2019


Article type: Communication
DOI: 10.1039/C9CC07069A
Chem. Commun., 2019, Advance Article

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    Catalyst-free phosphorylation of aryl halides with trialkyl phosphites through electrochemical reduction

    S. Wang, C. Yang, S. Sun and J. Wang, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC07069A

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