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Photoinduced-electron-transfer-driven surface modification to regulate adsorption behavior in a pyridinium-decorated metal–organic framework

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Abstract

Surface modification based on a photo-induced electron transfer (PET) reaction in a pyridinium-decorated MOF material was found to be effective in regulating adsorption capacity. The current system enables the adsorption behavior to be manipulated based on variable affinity toward guest molecules through the redistribution of charge population with the preservation of the original pore structure, which is different from the prevalent approaches depending on photoinduced changes in molecular configurations of the pore backbone.

Graphical abstract: Photoinduced-electron-transfer-driven surface modification to regulate adsorption behavior in a pyridinium-decorated metal–organic framework

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Publication details

The article was received on 19 Aug 2019, accepted on 30 Sep 2019 and first published on 02 Oct 2019


Article type: Communication
DOI: 10.1039/C9CC06416H
Chem. Commun., 2019, Advance Article

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    Photoinduced-electron-transfer-driven surface modification to regulate adsorption behavior in a pyridinium-decorated metal–organic framework

    X. Yang, N. Gao, S. Ma, J. Cui, M. Jia and J. Zhang, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC06416H

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