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Issue 70, 2019
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Diphosphene radical cations and dications with a π-conjugated C2P2C2-framework

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Abstract

The synthesis and characterization of the crystalline diphosphene radical cations [{(NHC)C(Ph)}P]2(GaCl4) (NHC = IPr = C{(NDipp)CH}23, SIPr = C{(NDipp)CH2}24; Dipp = 2,6-iPr2C6H3) and dications [{(NHC)C(Ph)}P]2(GaCl4)2 (NHC = IPr 5, SIPr 6) featuring a π-conjugated C2P2C2-framework has been reported.

Graphical abstract: Diphosphene radical cations and dications with a π-conjugated C2P2C2-framework

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Publication details

The article was received on 19 Jun 2019, accepted on 05 Aug 2019 and first published on 05 Aug 2019


Article type: Communication
DOI: 10.1039/C9CC04701H
Chem. Commun., 2019,55, 10408-10411

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    Diphosphene radical cations and dications with a π-conjugated C2P2C2-framework

    M. K. Sharma, D. Rottschäfer, S. Blomeyer, B. Neumann, H. Stammler, M. van Gastel, A. Hinz and R. S. Ghadwal, Chem. Commun., 2019, 55, 10408
    DOI: 10.1039/C9CC04701H

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