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Abstract | Cited by

Self-assembly reactions of CoII ions in the presence of the 2,2-bipyrimidine (bpym) ligand produced both a dinuclear and an octanuclear cation with the nuclearity being governed by hydrogen-bonding versus anion–π interactions between the anions and the ligands.

Graphical abstract: A Co8 metallacycle stabilized by double anion–π interactions

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