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Issue 77, 2019
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Intermolecular coupling and intramolecular cyclization of aryl nitriles on Au(111)

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Abstract

The on-surface dimerization reaction of an organic nitrile on Au(111) is reported. The formation of the product, which contains five newly formed σ-bonds and a diazapyrene core structure, was investigated and characterized by scanning tunneling microscopy. Experimental and computational studies of reference compounds support our findings.

Graphical abstract: Intermolecular coupling and intramolecular cyclization of aryl nitriles on Au(111)

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Publication details

The article was received on 03 May 2019, accepted on 29 Aug 2019 and first published on 30 Aug 2019


Article type: Communication
DOI: 10.1039/C9CC03418H
Chem. Commun., 2019,55, 11611-11614

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    Intermolecular coupling and intramolecular cyclization of aryl nitriles on Au(111)

    H. Klaasen, L. Liu, H. Gao, L. Viergutz, P. A. Held, T. Knecht, X. Meng, M. C. Börner, D. Barton, S. Amirjalayer, J. Neugebauer, A. Studer and H. Fuchs, Chem. Commun., 2019, 55, 11611
    DOI: 10.1039/C9CC03418H

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