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Issue 77, 2019
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Intermolecular coupling and intramolecular cyclization of aryl nitriles on Au(111)

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Abstract

The on-surface dimerization reaction of an organic nitrile on Au(111) is reported. The formation of the product, which contains five newly formed σ-bonds and a diazapyrene core structure, was investigated and characterized by scanning tunneling microscopy. Experimental and computational studies of reference compounds support our findings.

Graphical abstract: Intermolecular coupling and intramolecular cyclization of aryl nitriles on Au(111)

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Article information


Submitted
03 May 2019
Accepted
29 Aug 2019
First published
30 Aug 2019

Chem. Commun., 2019,55, 11611-11614
Article type
Communication

Intermolecular coupling and intramolecular cyclization of aryl nitriles on Au(111)

H. Klaasen, L. Liu, H. Gao, L. Viergutz, P. A. Held, T. Knecht, X. Meng, M. C. Börner, D. Barton, S. Amirjalayer, J. Neugebauer, A. Studer and H. Fuchs, Chem. Commun., 2019, 55, 11611
DOI: 10.1039/C9CC03418H

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