A multifunctional triazine-based nanoporous polymer as a versatile organocatalyst for CO2 utilization and C–C bond formation

Ruchi Sharma; Ankushi Bansal; C. N. Ramachandran; Paritosh Mohanty

doi:10.1039/C9CC04975D

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A multifunctional triazine-based nanoporous polymer as a versatile organocatalyst for CO₂ utilization and C–C bond formation†

Ruchi Sharma,

^a Ankushi Bansal,

^a C. N. Ramachandran

^b and Paritosh Mohanty

*^a

Author affiliations

* Corresponding authors

^a Functional Materials Laboratory, Department of Chemistry, IIT Roorkee, Roorkee-247667, Uttarakhand, India
E-mail: pmfcy@iitr.ac.in, paritosh75@gmail.com

^b Theoretical and Computational Chemistry Laboratory, Department of Chemistry, IIT Roorkee, Uttarakhand-247667, India

Abstract

A triazine-based nanoporous multifunctional polymer with a SA_BET of 304 m² g⁻¹ has shown versatile catalytic activity in the conversion of CO₂ to cyclic carbonates at 4 bar with almost 100% yield and selectivity, and in the conversion of CO₂ to methanol and methane electrochemically. Additionally, it also catalyzes C–C bond formation via the Knoevenagel reaction.

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Article information

DOI: https://doi.org/10.1039/C9CC04975D
Article type: Communication
Submitted: 28 Jun 2019
Accepted: 28 Aug 2019
First published: 28 Aug 2019

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Chem. Commun., 2019,55, 11607-11610

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A multifunctional triazine-based nanoporous polymer as a versatile organocatalyst for CO₂ utilization and C–C bond formation

R. Sharma, A. Bansal, C. N. Ramachandran and P. Mohanty, Chem. Commun., 2019, 55, 11607 DOI: 10.1039/C9CC04975D

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