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Abstract | Cited by

π-Conjugated porphyrin-containing hollow structures with defined axis-length were successfully synthesized by a two-step template method, i.e., template-assisted cyclization and oligomerization. During the oligomerization, templates played important roles in controlling the reaction rates and the axis lengths. The hollow structures exhibited an extended effective π-conjugation because of the high coplanarity between porphyrins.

Graphical abstract: Two-step template method for synthesis of axis-length-controlled porphyrin-containing hollow structures

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