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Two-Step Template Method for Synthesis of Axis-Length-Controlled Porphyrin-Containing Hollow Structures

Abstract

π-Conjugated porphyrin-containing hollow structures with defined axis-length were successfully synthesized by a two-step template method, i.e., template-assisted cyclization and oligomerization. During the oligomerization, templates played important roles in controlling the reaction rates and the axis lengths. The hollow structures exhibited an extended effective π-conjugation because of the high coplanarity between porphyrins.

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Publication details

The article was received on 13 Apr 2019, accepted on 13 May 2019 and first published on 13 May 2019


Article type: Communication
DOI: 10.1039/C9CC02866H
Chem. Commun., 2019, Accepted Manuscript

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    Two-Step Template Method for Synthesis of Axis-Length-Controlled Porphyrin-Containing Hollow Structures

    Y. Chiba, Y. Oka, H. Masai, W. Matsuda, T. Fujihara, Y. Tsuji and J. Terao, Chem. Commun., 2019, Accepted Manuscript , DOI: 10.1039/C9CC02866H

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