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Issue 41, 2019
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Rhenium is different: CO tetramerization induced by a divalent lanthanide complex in rhenium carbonyls

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Abstract

The reduction of M2(CO)10 (M = Mn, Re) with different divalent lanthanide (Ln = Sm, Yb) compounds was investigated. Depending on the steric demand of the ligand, either unusual CO tetramerization or formation of a new Re carbonyl anion occurred in the case of Re. Theoretical calculations were performed for a better understanding of the nature of bonding in the newly formed species.

Graphical abstract: Rhenium is different: CO tetramerization induced by a divalent lanthanide complex in rhenium carbonyls

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Supplementary files

Article information


Submitted
26 Mar 2019
Accepted
18 Apr 2019
First published
30 Apr 2019

This article is Open Access

Chem. Commun., 2019,55, 5765-5768
Article type
Communication

Rhenium is different: CO tetramerization induced by a divalent lanthanide complex in rhenium carbonyls

R. Yadav, T. Simler, M. T. Gamer, R. Köppe and P. W. Roesky, Chem. Commun., 2019, 55, 5765
DOI: 10.1039/C9CC02350J

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