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Issue 49, 2019
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Single-component frameworks for heterogeneous catalytic hydrolysis of organophosphorous compounds in pure water

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Abstract

Amine modified Zr6-based metal–organic frameworks (MOFs) were synthesized through solvent-assisted linker incorporation (SALI) and utilized as single-component heterogeneous catalysts for the hydrolysis of organophosphorous compounds under solely aqueous conditions at room temperature. These materials display unprecidentedly fast catalytic hydrolysis for dimethyl p-nitrophenyl phosphate (DMNP) and nerve agent VX without the use of a buffered solution.

Graphical abstract: Single-component frameworks for heterogeneous catalytic hydrolysis of organophosphorous compounds in pure water

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Publication details

The article was received on 21 Mar 2019, accepted on 16 May 2019 and first published on 16 May 2019


Article type: Communication
DOI: 10.1039/C9CC02236H
Chem. Commun., 2019,55, 7005-7008

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    Single-component frameworks for heterogeneous catalytic hydrolysis of organophosphorous compounds in pure water

    S. J. Garibay, O. K. Farha and J. B. DeCoste, Chem. Commun., 2019, 55, 7005
    DOI: 10.1039/C9CC02236H

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