Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.


Issue 22, 2019
Previous Article Next Article

Molecular doping: accessing the first carborane-substituted 1,2,3-triphospholanide via insertion of P into a P−P bond

Author affiliations

Abstract

Insertion of a P anion into a P–P bond yielding the first carborane-substituted 1,2,3-triphospholanide 1 was achieved by treating a carborane-substitued 1,2-diphosphetane with sodium phosphaethynolate. The triphospholanide 1 can serve as a versatile nucleophilic building block for unprecedent functionalised triphospholanes and carborane-substituted polyphosphanes.

Graphical abstract: Molecular doping: accessing the first carborane-substituted 1,2,3-triphospholanide via insertion of P− into a P−P bond

Back to tab navigation

Supplementary files

Article information


Submitted
09 Jan 2019
Accepted
03 Feb 2019
First published
04 Feb 2019

This article is Open Access

Chem. Commun., 2019,55, 3187-3190
Article type
Communication

Molecular doping: accessing the first carborane-substituted 1,2,3-triphospholanide via insertion of P into a P−P bond

P. Coburger, H. Grützmacher and E. Hey-Hawkins, Chem. Commun., 2019, 55, 3187
DOI: 10.1039/C9CC00205G

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material.

Reproduced material should be attributed as follows:

  • For reproduction of material from NJC:
    [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
  • For reproduction of material from PCCP:
    [Original citation] - Published by the PCCP Owner Societies.
  • For reproduction of material from PPS:
    [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
  • For reproduction of material from all other RSC journals:
    [Original citation] - Published by The Royal Society of Chemistry.

Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.


Social activity

Search articles by author

Spotlight

Advertisements