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Molecular doping: accessing the first carborane-substituted 1,2,3-triphospholanide via insertion of P into a P−P bond

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Abstract

Insertion of a P anion into a P–P bond yielding the first carborane-substituted 1,2,3-triphospholanide 1 was achieved by treating a carborane-substitued 1,2-diphosphetane with sodium phosphaethynolate. The triphospholanide 1 can serve as a versatile nucleophilic building block for unprecedent functionalised triphospholanes and carborane-substituted polyphosphanes.

Graphical abstract: Molecular doping: accessing the first carborane-substituted 1,2,3-triphospholanide via insertion of P− into a P−P bond

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Publication details

The article was received on 09 Jan 2019, accepted on 03 Feb 2019 and first published on 04 Feb 2019


Article type: Communication
DOI: 10.1039/C9CC00205G
Citation: Chem. Commun., 2019, Advance Article

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    Molecular doping: accessing the first carborane-substituted 1,2,3-triphospholanide via insertion of P into a P−P bond

    P. Coburger, H. Grützmacher and E. Hey-Hawkins, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC00205G

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