We report the sensitivity of the membrane asymmetry of ABC (PEO-b-PCL-b-PMOXA) polymersomes towards the end-group modification of a shorter C block. While a non-modified ABC polymer formed polymersomes with the A block outside and the C block inside, a mixture of ABC and ABC-biotin formed polymersomes with the C block outside.
E. V. Konishcheva, D. Daubian, S. Rigo and W. P. Meier, Chem. Commun., 2019, 55, 1148 DOI: 10.1039/C8CC09659G
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