Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Wednesday 27th March 2019 from 11:00 AM to 1:00 PM (GMT).

During this time our website performance may be temporarily affected. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 8, 2019
Previous Article Next Article

Alkynylation of graphene via the Sonogashira C–C cross-coupling reaction on fluorographene

Author affiliations

Abstract

We report successful grafting of alkynyl groups onto graphene via the Sonogashira reaction between fluorographene and terminal alkynes. Theoretical calculations revealed that fluorographene can efficiently bind and oxidize the palladium catalyst on electrophilic sites activated by fluorine atoms. This paves the way towards conductive and mechanically robust 3D covalent networks.

Graphical abstract: Alkynylation of graphene via the Sonogashira C–C cross-coupling reaction on fluorographene

Back to tab navigation

Supplementary files

Publication details

The article was received on 24 Oct 2018, accepted on 05 Dec 2018 and first published on 07 Jan 2019


Article type: Communication
DOI: 10.1039/C8CC08492K
Citation: Chem. Commun., 2019,55, 1088-1091
  • Open access: Creative Commons BY-NC license
  •   Request permissions

    Alkynylation of graphene via the Sonogashira C–C cross-coupling reaction on fluorographene

    D. D. Chronopoulos, M. Medved’, P. Błoński, Z. Nováček, P. Jakubec, O. Tomanec, A. Bakandritsos, V. Novotná, R. Zbořil and M. Otyepka, Chem. Commun., 2019, 55, 1088
    DOI: 10.1039/C8CC08492K

    This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material and it is not used for commercial purposes.

    Reproduced material should be attributed as follows:

    • For reproduction of material from NJC:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
    • For reproduction of material from PCCP:
      [Original citation] - Published by the PCCP Owner Societies.
    • For reproduction of material from PPS:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
    • For reproduction of material from all other RSC journals:
      [Original citation] - Published by The Royal Society of Chemistry.

    Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.

Search articles by author

Spotlight

Advertisements