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A clickable caging group as a new platform for modular caged compounds with improved photochemical properties

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Abstract

A 6-bromo-7-hydroxycoumarin-4-ylmethyl (Bhc) caged compound having a click-modifiable chemical handle was designed and synthesized. This molecule was applied to the synthesis of modular caged paclitaxels (PTXs) in which additional functional units could be easily installed. This system was used to prepare water-soluble caged PTXs with improved photolysis efficiencies.

Graphical abstract: A clickable caging group as a new platform for modular caged compounds with improved photochemical properties

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Publication details

The article was received on 08 Oct 2018, accepted on 13 Nov 2018 and first published on 14 Nov 2018


Article type: Communication
DOI: 10.1039/C8CC07981A
Citation: Chem. Commun., 2019, Advance Article
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    A clickable caging group as a new platform for modular caged compounds with improved photochemical properties

    A. Z. Suzuki, R. Sekine, S. Takeda, R. Aikawa, Y. Shiraishi, T. Hamaguchi, H. Okuno, H. Tamamura and T. Furuta, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C8CC07981A

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