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Issue 27, 2019
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A mixed-spin spin-crossover thiozolylimine [Fe4L6]8+ cage

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Abstract

The self-assembly of a mixed-spin [Fe4L6]8+ tetrahedral cage is reported. The cage undergoes temperature induced spin-crossover with a 29 K hystereisis. Variable temperature X-ray photoelectron spectroscopy (VT-XPS), combined with SQUID data, allowed differentiation between the surface and bulk magnetic properties.

Graphical abstract: A mixed-spin spin-crossover thiozolylimine [Fe4L6]8+ cage

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Supplementary files

Article information


Submitted
10 May 2019
Accepted
10 Jun 2019
First published
10 Jun 2019

Dalton Trans., 2019,48, 9935-9938
Article type
Communication

A mixed-spin spin-crossover thiozolylimine [Fe4L6]8+ cage

L. Li, A. R. Craze, O. Mustonen, H. Zenno, J. J. Whittaker, S. Hayami, L. F. Lindoy, C. E. Marjo, J. K. Clegg, J. R. Aldrich-Wright and F. Li, Dalton Trans., 2019, 48, 9935
DOI: 10.1039/C9DT01947B

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