Issue 27, 2019
From the journal:

Dalton Transactions

Syntheses and magnetic properties of high-dimensional cucurbit[6]uril-based metal–organic rotaxane frameworks†

Xue-Song Wu,a   Hong-Fei Bao,b   Fu-Long Zhu,b   Jing Sun,*a   Xin-Long Wang ORCID logo ab  and  Zhong-Min Su ORCID logo *ab  

* Corresponding authors

a Jilin Provincial Science and Technology Innovation Center of Optical Materials and Chemistry, School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun, Jilin, P. R. China
E-mail: sj-cust@126.com, zmsu@nenu.edu.cn

b National & Local United Engineering Laboratory for Power Battery Institution, Northeast Normal University, Changchun, Jilin, P.R. China

Abstract

Three new high-dimensional cucurbit[6]-based metal–organic rotaxane frameworks [Co2(PR43)(BDC)2Cl2]·4H2O (1), [Co2(PR43)(BTC)2]·6H2O (2) and [Co2(PR43)(BPT)2]·20H2O (3) were obtained via the hydrothermal synthesis method. Compound 1 comprised a two-dimensional layered structure, while compounds 2 and 3 exhibited three-dimensional pillared structures. All the compounds showed good thermal stabilities. Furthermore, the magnetic properties of compounds 1–3 were also investigated in detail.

Graphical abstract: Syntheses and magnetic properties of high-dimensional cucurbit[6]uril-based metal–organic rotaxane frameworks

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Article information

DOI
https://doi.org/10.1039/C9DT01544B
Article type
Communication
Submitted
11 Apr 2019
Accepted
31 May 2019
First published
03 Jun 2019

Dalton Trans., 2019,48, 9939-9943

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Syntheses and magnetic properties of high-dimensional cucurbit[6]uril-based metal–organic rotaxane frameworks

X. Wu, H. Bao, F. Zhu, J. Sun, X. Wang and Z. Su, Dalton Trans., 2019, 48, 9939 DOI: 10.1039/C9DT01544B

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