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Issue 71, 2019
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Catalytic cross-dimerisation giving reactive borylated polyenes toward cross-coupling

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Abstract

A series of borylated conjugated trienes and skipped dienes is prepared by Ru-catalysed cross-dimerisation using alkynyl-, dienyl-, and vinyl boronates. These products are used as synthetic building blocks for polyene substructures by subsequent Pd-catalysed cross-coupling in a one-pot vessel without deprotection.

Graphical abstract: Catalytic cross-dimerisation giving reactive borylated polyenes toward cross-coupling

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Publication details

The article was received on 30 Jul 2019, accepted on 09 Aug 2019 and first published on 16 Aug 2019


Article type: Communication
DOI: 10.1039/C9CC05930J
Chem. Commun., 2019,55, 10527-10530

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    Catalytic cross-dimerisation giving reactive borylated polyenes toward cross-coupling

    M. Hirano, A. Kuramochi, K. Shimada, N. Komine, S. Kiyota and S. A. Westcott, Chem. Commun., 2019, 55, 10527
    DOI: 10.1039/C9CC05930J

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