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Issue 61, 2019
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Icosahedral carboranes as scaffolds for congested regioselective polyaryl compounds: the distinct distance tuning of C–C and its antipodal B–B

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Abstract

Four-fold aryl substituted o-carborane derivatives with defined patterns of substitution at the antipodal region of the cluster carbon atoms have been achieved. It is proven that this region is congested but lacks steric hindrance. Also, the two antipodal sites Cc–Cc and B9–B12 are affected very distinctly by electron donor substituents.

Graphical abstract: Icosahedral carboranes as scaffolds for congested regioselective polyaryl compounds: the distinct distance tuning of C–C and its antipodal B–B

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Publication details

The article was received on 12 Jun 2019, accepted on 21 Jun 2019 and first published on 25 Jun 2019


Article type: Communication
DOI: 10.1039/C9CC04526K
Chem. Commun., 2019,55, 8927-8930
  • Open access: Creative Commons BY-NC license
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    Icosahedral carboranes as scaffolds for congested regioselective polyaryl compounds: the distinct distance tuning of C–C and its antipodal B–B

    Z. Kelemen, A. Pepiol, M. Lupu, R. Sillanpää, M. M. Hänninen, F. Teixidor and C. Viñas, Chem. Commun., 2019, 55, 8927
    DOI: 10.1039/C9CC04526K

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