Ba3B10O17F2·0.1KF: the first mixed alkali/alkaline-earth metal fluorooxoborate with unprecedented double-layered B–O/F anionic arrangement

Yahui Li; Hongwei Yu; Guopeng Han; Hao Li; Zhihua Yang; Shilie Pan

doi:10.1039/C9CC02808K

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Ba₃B₁₀O₁₇F₂·0.1KF: the first mixed alkali/alkaline-earth metal fluorooxoborate with unprecedented double-layered B–O/F anionic arrangement†

Yahui Li,‡^ab Hongwei Yu,‡^a Guopeng Han,^ab Hao Li,^ab Zhihua Yang

^a and Shilie Pan

*^a

Author affiliations

* Corresponding authors

^a CAS Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics & Chemistry, CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, 40-1 South Beijing Road, Urumqi 830011, China
E-mail: slpan@ms.xjb.ac.cn

^b Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

The diverse oxyfluoride species and vast number of different topological arrangements lead to fluorooxoborates’ structural beauty and richness. Herein, the first mixed alkali/alkaline-earth metal fluorooxoborate Ba₃B₁₀O₁₇F₂·0.1KF was successfully synthesized and systemically characterized. Its most important structural feature is an unprecedented double-layered B–O/F anionic arrangement.

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Article information

DOI: https://doi.org/10.1039/C9CC02808K
Article type: Communication
Submitted: 12 Apr 2019
Accepted: 28 Jun 2019
First published: 04 Jul 2019

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Chem. Commun., 2019,55, 8923-8926

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Ba₃B₁₀O₁₇F₂·0.1KF: the first mixed alkali/alkaline-earth metal fluorooxoborate with unprecedented double-layered B–O/F anionic arrangement

Y. Li, H. Yu, G. Han, H. Li, Z. Yang and S. Pan, Chem. Commun., 2019, 55, 8923 DOI: 10.1039/C9CC02808K

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