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Issue 47, 2019
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Two-step template method for synthesis of axis-length-controlled porphyrin-containing hollow structures†

Yusuke Chiba,‡a   Yuki Oka,b   Hiroshi Masai,b   Wakana Matsuda,a   Tetsuaki Fujihara, ORCID logo a   Yasushi Tsuji ORCID logo a  and  Jun Terao ORCID logo *bc  
Author affiliations

* Corresponding authors

a Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan

b Graduate School of Arts and Sciences, The University of Tokyo, Meguro-ku, Tokyo 153-8902, Japan
E-mail: cterao@mail.ecc.u-tokyo.ac.jp

c School of Science, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, Japan

Abstract

π-Conjugated porphyrin-containing hollow structures with defined axis-length were successfully synthesized by a two-step template method, i.e., template-assisted cyclization and oligomerization. During the oligomerization, templates played important roles in controlling the reaction rates and the axis lengths. The hollow structures exhibited an extended effective π-conjugation because of the high coplanarity between porphyrins.

Graphical abstract: Two-step template method for synthesis of axis-length-controlled porphyrin-containing hollow structures

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Article information

https://doi.org/10.1039/C9CC02866H
Submitted
13 Apr 2019
Accepted
13 May 2019
First published
13 May 2019
Chem. Commun., 2019,55, 6755-6758
Article type
Communication
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Two-step template method for synthesis of axis-length-controlled porphyrin-containing hollow structures

Y. Chiba, Y. Oka, H. Masai, W. Matsuda, T. Fujihara, Y. Tsuji and J. Terao, Chem. Commun., 2019, 55, 6755
DOI: 10.1039/C9CC02866H

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