Issue 31, 2019

A route to a cyclobutane-linked double-looped system via a helical macrocycle

Abstract

Macrocycles built of carbazole and pyridine fragments with alkene/alkane linkers constitute a helical structure as documented structurally and spectroscopically. The ‘solid-state’ prearrangement observed for two C[double bond, length as m-dash]C bonds leads to unprecedented transformation to a cyclobutane in a head-to-tail (rtct) geometry with two macrocyclic loops in a perpendicular orientation.

Graphical abstract: A route to a cyclobutane-linked double-looped system via a helical macrocycle

Supplementary files

Article information

Article type
Communication
Submitted
11 Feb 2019
Accepted
22 Mar 2019
First published
23 Mar 2019

Chem. Commun., 2019,55, 4558-4561

A route to a cyclobutane-linked double-looped system via a helical macrocycle

J. Klajn, W. Stawski, P. J. Chmielewski, J. Cybińska and M. Pawlicki, Chem. Commun., 2019, 55, 4558 DOI: 10.1039/C9CC01201J

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