Stereoselective degradation behaviour of carfentrazone-ethyl and its metabolite carfentrazone in soils

Abstract

The stereoselective environmental behaviour of carfentrazone-ethyl and its metabolite carfentrazone enantiomer in three types of soil were studied under aerobic conditions. Under aerobic conditions, significant stereoselective difference in the degradation behaviour of carfentrazone-ethyl and its metabolite carfentrazone enantiomer was observed in Jiangxi red soil, Jilin black soil and Anhui paddy soil. The EF values of the carfentrazone-ethyl enantiomers in Anhui paddy soil, Jilin black soil, and Jiangxi red soil were 0.67, 0.65 and 0.57, respectively. The EF values of the carfentrazone enantiomer in the three types of soil were 0.75, 0.80 and 0.76. No bidirectional chiral inversion of enantiopure carfentrazone-ethyl and carfentrazone enantiomers was observed in Jilin soil. As a result, R-(+)-carfentrazone-ethyl and S-(+)-carfentrazone in soil would be preferentially degraded, while S-(−)-carfentrazone-ethyl and R-(−)-carfentrazone were enriched. The results found in this paper could provide more scientific guidance for the risk assessments of carfentrazone-ethyl from a chiral perspective.