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Reusable Fe2O3-nanoparticle catalysed efficient and selective hydroboration of carbonyl compounds

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Abstract

The first Fe2O3-nanoparticle catalysed hydroboration of aromatic and aliphatic aldehydes and ketones with HBpin (pin = OCMe2CMe2O) is reported. The reaction proceeds under mild conditions (room temperature) and is moderately sensitive to air. This process is applicable to a broad range of substrates with high functional group compatibility. Moreover, aldehydes are selectively hydroborated over other reducible functional groups, such as ketone, nitrile, hydroxide, alkene, amide, ester, nitro and halide groups.

Graphical abstract: Reusable Fe2O3-nanoparticle catalysed efficient and selective hydroboration of carbonyl compounds

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Publication details

The article was received on 22 Aug 2018, accepted on 25 Oct 2018 and first published on 25 Oct 2018


Article type: Research Article
DOI: 10.1039/C8QO00912K
Citation: Org. Chem. Front., 2018, Advance Article
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    Reusable Fe2O3-nanoparticle catalysed efficient and selective hydroboration of carbonyl compounds

    M. L. Shegavi, A. Baishya, K. Geetharani and S. K. Bose, Org. Chem. Front., 2018, Advance Article , DOI: 10.1039/C8QO00912K

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