Issue 24, 2018

Reusable Fe2O3-nanoparticle catalysed efficient and selective hydroboration of carbonyl compounds

Abstract

The first Fe2O3-nanoparticle catalysed hydroboration of aromatic and aliphatic aldehydes and ketones with HBpin (pin = OCMe2CMe2O) is reported. The reaction proceeds under mild conditions (room temperature) and is moderately sensitive to air. This process is applicable to a broad range of substrates with high functional group compatibility. Moreover, aldehydes are selectively hydroborated over other reducible functional groups, such as ketone, nitrile, hydroxide, alkene, amide, ester, nitro and halide groups.

Graphical abstract: Reusable Fe2O3-nanoparticle catalysed efficient and selective hydroboration of carbonyl compounds

Supplementary files

Article information

Article type
Research Article
Submitted
22 Aug 2018
Accepted
25 Oct 2018
First published
25 Oct 2018

Org. Chem. Front., 2018,5, 3520-3525

Reusable Fe2O3-nanoparticle catalysed efficient and selective hydroboration of carbonyl compounds

M. L. Shegavi, A. Baishya, K. Geetharani and S. K. Bose, Org. Chem. Front., 2018, 5, 3520 DOI: 10.1039/C8QO00912K

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