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Issue 18, 2018
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Photoinduced fragmentation-rearrangement sequence of cycloketoxime esters

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Abstract

A novel rearrangement of cycloketoxime esters to cyano-containing benzoates beyond the traditional Beckmann and Neber rearrangement process has been established in the presence of photocatalysis catalysis. This SET-induced structural reorganization of cycloketoxime esters is perfectly an atom economic process and distinguished by mild and safe reaction conditions that avoid acid, base and toxic cyanide salts.

Graphical abstract: Photoinduced fragmentation-rearrangement sequence of cycloketoxime esters

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Supplementary files

Article information


Submitted
21 Jul 2018
Accepted
16 Aug 2018
First published
16 Aug 2018

Org. Chem. Front., 2018,5, 2719-2722
Article type
Research Article

Photoinduced fragmentation-rearrangement sequence of cycloketoxime esters

B. Zhao, C. Chen, J. Lv, Z. Li, Y. Yuan and Z. Shi, Org. Chem. Front., 2018, 5, 2719
DOI: 10.1039/C8QO00747K

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