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Visible light-induced free radical promoted cationic polymerization using organotellurium compounds

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Abstract

Organotellurium-mediated polymerization of cyclohexene oxide (CHO), isobutyl vinyl ether (IBVE) and N-vinylcarbazole (NVC) in the presence of diphenyliodonium hexafluorophosphate (DPI) was accomplished under visible light and sunlight. The chain-transfer agent (CTA) ethyl 2-methyl-2-methyltellanylpropionate (EMPTeMe) and poly(methyl methacrylate) with an organotellurium group at the chain end (PMMATeMe) were used as photoinitiators.

Graphical abstract: Visible light-induced free radical promoted cationic polymerization using organotellurium compounds

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Publication details

The article was received on 23 Sep 2018, accepted on 03 Nov 2018 and first published on 05 Nov 2018


Article type: Communication
DOI: 10.1039/C8PY01380B
Citation: Polym. Chem., 2018, Advance Article
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    Visible light-induced free radical promoted cationic polymerization using organotellurium compounds

    K. Kaya, M. Seba, T. Fujita, S. Yamago and Y. Yagci, Polym. Chem., 2018, Advance Article , DOI: 10.1039/C8PY01380B

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