Issue 48, 2018
From the journal:

Polymer Chemistry

Visible light-induced free radical promoted cationic polymerization using organotellurium compounds†

Kerem Kaya, ORCID logo a   Mustafa Seba,a   Takehiro Fujita,b   Shigeru Yamago ORCID logo *b  and  Yusuf Yagci ORCID logo *ac  

* Corresponding authors

a Istanbul Technical University, Faculty of Science and Literature, Chemistry Department, Maslak, Istanbul, Turkey
E-mail: yusuf@itu.edu.tr

b Kyoto University, Institute for Chemical Research, Uji 611-0011, Japan
E-mail: yamago@scl.kyoto-u.ac.jp

c King Abdulaziz University, Chemistry Department, Faculty of Science, Jeddah, Saudi Arabia

Abstract

Organotellurium-mediated polymerization of cyclohexene oxide (CHO), isobutyl vinyl ether (IBVE) and N-vinylcarbazole (NVC) in the presence of diphenyliodonium hexafluorophosphate (DPI) was accomplished under visible light and sunlight. The chain-transfer agent (CTA) ethyl 2-methyl-2-methyltellanylpropionate (EMPTeMe) and poly(methyl methacrylate) with an organotellurium group at the chain end (PMMATeMe) were used as photoinitiators.

Graphical abstract: Visible light-induced free radical promoted cationic polymerization using organotellurium compounds

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Article information

DOI
https://doi.org/10.1039/C8PY01380B
Article type
Communication
Submitted
23 Sep 2018
Accepted
03 Nov 2018
First published
05 Nov 2018

Polym. Chem., 2018,9, 5639-5643

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Visible light-induced free radical promoted cationic polymerization using organotellurium compounds

K. Kaya, M. Seba, T. Fujita, S. Yamago and Y. Yagci, Polym. Chem., 2018, 9, 5639 DOI: 10.1039/C8PY01380B

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