Issue 13, 2018

Halogen bonding two-point recognition with terphenyl derivatives

Abstract

Two-point recognition involving neutral terphenyl-based halogen bond donors (halogen-based Lewis acids) was investigated. Oxadiazole and pyridazole derivatives were identified by DFT as suitable binding partners, even though gas-phase binding was weak. X-ray studies provided convincing evidence of two-point binding in the solid state, while solution data hinted at weak association.

Graphical abstract: Halogen bonding two-point recognition with terphenyl derivatives

Supplementary files

Article information

Article type
Letter
Submitted
26 Feb 2018
Accepted
06 Apr 2018
First published
12 Apr 2018

New J. Chem., 2018,42, 10476-10480

Halogen bonding two-point recognition with terphenyl derivatives

J. Stoesser, G. Rojas, D. Bulfield, P. I. Hidalgo, J. Pasán, C. Ruiz-Pérez, C. A. Jiménez and S. M. Huber, New J. Chem., 2018, 42, 10476 DOI: 10.1039/C8NJ00962G

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