Issue 13, 2018
From the journal:

New Journal of Chemistry

Various types of non-covalent interactions contributing towards crystal packing of halogenated diphospha-dicarbaborane with an open pentagonal belt†

Josef Holub,a   Zdeňka Růžičková,b   Pavel Hobza, ORCID logo *c   Jindřich Fanfrlík, ORCID logo *c   Drahomír Hnyk ORCID logo *a  and  Aleš Růžička*b  

* Corresponding authors

a Institute of Inorganic Chemistry of the Czech Academy of Sciences, 250 68 Husinec-Řež, Czech Republic
E-mail: hnyk@iic.cas.cz

b Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, 53210 Pardubice, Czech Republic
E-mail: ales.ruzicka@upce.cz

c Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo nam. 2, 166 10 Prague 6, Czech Republic
E-mail: hobza@uochb.cas.cz, fanfrlik@uochb.cas.cz

Abstract

We have prepared 3-Cl-10-I-nido-7,8,9,11-P2C2B7H7 by the reaction of 3-Cl-nido-7,8,9,11-P2C2B7H8 with I2 in the presence of AlCl3. The product was obtained in a yield of 49% and was characterized by NMR spectroscopy and X-ray crystallography. Quantum chemical calculations have demonstrated that the crystal structure is stabilized by hydrogen, dihydrogen and pnictogen bonds.

Graphical abstract: Various types of non-covalent interactions contributing towards crystal packing of halogenated diphospha-dicarbaborane with an open pentagonal belt

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Article information

DOI
https://doi.org/10.1039/C8NJ00450A
Article type
Letter
Submitted
25 Jan 2018
Accepted
19 Mar 2018
First published
29 Mar 2018
This article is Open Access
Creative Commons BY-NC license

New J. Chem., 2018,42, 10481-10483

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Various types of non-covalent interactions contributing towards crystal packing of halogenated diphospha-dicarbaborane with an open pentagonal belt

J. Holub, Z. Růžičková, P. Hobza, J. Fanfrlík, D. Hnyk and A. Růžička, New J. Chem., 2018, 42, 10481 DOI: 10.1039/C8NJ00450A

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