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Issue 36, 2018
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Solvent-induced ion separation of a beryllium scorpionate complex

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Abstract

Spontaneous ion separation of the scorpionate beryllium complex, TpBeI 1 (Tp = 1-trispyrazolylborate), occurs upon treatment with THF, yielding [TpBe(thf)]I 2, which was characterized by heteronuclear NMR spectroscopy (1H, 9Be, 13C) and structurally characterized by single crystal X-ray diffraction. 2 represents a rare example of a structurally characterized monocationic beryllium complex, and to the best of our knowledge, the synthesis of 2 by a solvent-induced ion separation has previously only been observed in the reactions of beryllium dihalides with strong Lewis bases.

Graphical abstract: Solvent-induced ion separation of a beryllium scorpionate complex

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Supplementary files

Article information


Submitted
24 Apr 2018
Accepted
09 May 2018
First published
11 May 2018

Dalton Trans., 2018,47, 12511-12515
Article type
Communication

Solvent-induced ion separation of a beryllium scorpionate complex

D. Naglav, B. Tobey, K. Dzialkowski, D. Bläser, C. Wölper, G. Jansen and S. Schulz, Dalton Trans., 2018, 47, 12511
DOI: 10.1039/C8DT01640B

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