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Dimethylamine Substituted Bisbenzocoumarins: Solvatochromic, Mechanochromic and Acidochromic properties

Abstract

Stimuli-responsive luminescent materials have attracted considerable attention in recent years because of their potential application in various fields. In this work, dimethylamine substituted bisbenzocoumarins derivatives (DB-Cn) are synthesized and their optical properties are investigated. These molecules show solvatochromism and mechanochromic properties. Powder wide-angle X-ray diffraction and differential scanning calorimetry curves reveal that the initial crystalline states are transformed to amorphous states under various external stimuli. Single crystal X-ray analysis of DB-C2 reveals that the destruction of the crystal conformation and the changes of intermolecular π-π stacking interactions could be responsible for the red-shifted emission. Further investigation revealed that DB-C2 showed acidochromic properties and could be utilized as security ink. The control 1H NMR experiment reveals that the protonation of the aromatic amines is essential for the acidochromic properties. This work provides the information on the mechanism study of stimuli-responsive luminescent properties of binaphthalene-type luminescent materials and expands the potential application of these materials.

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Publication details

The article was received on 24 Jun 2018, accepted on 07 Aug 2018 and first published on 07 Aug 2018


Article type: Paper
DOI: 10.1039/C8CE01034J
Citation: CrystEngComm, 2018, Accepted Manuscript
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    Dimethylamine Substituted Bisbenzocoumarins: Solvatochromic, Mechanochromic and Acidochromic properties

    S. Chen, W. Liu, Z. Ge, W. Zhang, K. Wang and Z. Hu, CrystEngComm, 2018, Accepted Manuscript , DOI: 10.1039/C8CE01034J

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