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Regioselective copper-catalyzed aminoborylation of styrenes with bis(pinacolato)diboron and diazo compounds

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Abstract

A Cu(I)-catalyzed aminoborylation reaction of styrenes is reported. In this transformation, diazo compounds are used as the electrophilic amination agent. The in situ generated benzylcopper species is trapped by the electrophilic nitrogen terminus of the diazo substrate to afford borylated hydrazones in a regioselective manner.

Graphical abstract: Regioselective copper-catalyzed aminoborylation of styrenes with bis(pinacolato)diboron and diazo compounds

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Publication details

The article was received on 28 Sep 2018, accepted on 05 Oct 2018 and first published on 08 Oct 2018


Article type: Communication
DOI: 10.1039/C8CC07764A
Citation: Chem. Commun., 2018, Advance Article
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    Regioselective copper-catalyzed aminoborylation of styrenes with bis(pinacolato)diboron and diazo compounds

    J. Huo, Y. Xue and J. Wang, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC07764A

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