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Issue 86, 2018
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A photoredox catalyzed iminyl radical-triggered C–C bond cleavage/addition/Kornblum oxidation cascade of oxime esters and styrenes: synthesis of ketonitriles

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Abstract

A photoredox-catalyzed iminyl radical-triggered C–C bond cleavage/addition/Kornblum oxidation cascade of cycloketone oxime esters and styrenes in DMSO is described. This three-component, one-pot procedure features mild conditions, a broad substrate scope, and high functional group tolerance, providing an efficient approach to access diversely functionalized ketonitriles.

Graphical abstract: A photoredox catalyzed iminyl radical-triggered C–C bond cleavage/addition/Kornblum oxidation cascade of oxime esters and styrenes: synthesis of ketonitriles

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Publication details

The article was received on 31 Aug 2018, accepted on 08 Oct 2018 and first published on 08 Oct 2018


Article type: Communication
DOI: 10.1039/C8CC07072E
Citation: Chem. Commun., 2018,54, 12262-12265

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    A photoredox catalyzed iminyl radical-triggered C–C bond cleavage/addition/Kornblum oxidation cascade of oxime esters and styrenes: synthesis of ketonitriles

    B. He, X. Yu, P. Wang, J. Chen and W. Xiao, Chem. Commun., 2018, 54, 12262
    DOI: 10.1039/C8CC07072E

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