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Coinage metal complexes of NHC-stabilized silyliumylidene ions

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Abstract

The first silyliumylidene ion coinage metal complexes are reported. Treatment of N-heterocyclic carbene (NHC) stabilized silyliumylidene ions (R = m-Ter, Tipp) with transition metal precursors (CuCl, AgOTf, (Me2S)AuCl) yields the first silyliumylidene coinage metal (M = Cu, Ag, Au) complexes, which have been fully characterized including X-ray diffraction analyses.

Graphical abstract: Coinage metal complexes of NHC-stabilized silyliumylidene ions

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Publication details

The article was received on 27 Sep 2018, accepted on 18 Oct 2018 and first published on 18 Oct 2018


Article type: Communication
DOI: 10.1039/C8CC07754A
Citation: Chem. Commun., 2018, Advance Article
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    Coinage metal complexes of NHC-stabilized silyliumylidene ions

    P. Frisch and S. Inoue, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC07754A

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