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Issue 100, 2018
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Conjugated hybrid films based on a new polyoxotitanate monomer

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Abstract

Electropolymerisation of the novel polyoxotitanate (POT) hexamer [Ti(μ3-O)(OiPr)(TA)]6 (TA = thiophene-3-acetate) with 3,4-ethylenedioxythiophene (EDOT) gives films of hybrid conjugated copolymer, Poly-(EDOT-POT)s, the morphologies of which are, uniquely, influenced by the electropolymerisation potential. Nanoporous Poly-(EDOT-POT)-1 is a fast-ion electrode material and has improved electrochromic properties and significantly higher capacitance than that of the parent poly(3,4-ethylenedioxythiophene) (PEDOT).

Graphical abstract: Conjugated hybrid films based on a new polyoxotitanate monomer

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Publication details

The article was received on 18 Sep 2018, accepted on 26 Nov 2018 and first published on 27 Nov 2018


Article type: Communication
DOI: 10.1039/C8CC07527A
Citation: Chem. Commun., 2018,54, 14132-14135

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    Conjugated hybrid films based on a new polyoxotitanate monomer

    G. Liu, X. Yang, A. Bonnefont, Y. Lv, J. Chen, W. Dan, Z. Chen, L. Ruhlmann, D. S. Wright and C. Zhang, Chem. Commun., 2018, 54, 14132
    DOI: 10.1039/C8CC07527A

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