Issue 87, 2018
From the journal:

Chemical Communications

Spin–orbit charge transfer intersystem crossing in perylenemonoimide–phenothiazine compact electron donor–acceptor dyads†

Yingjie Zhao, ORCID logo ‡a   Ruomeng Duan,‡b   Jianzhang Zhao ORCID logo *a  and  Chen Li ORCID logo *b  

* Corresponding authors

a State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, E-208 West Campus, 2 Ling-Gong Road, Dalian 116024, P. R. China
E-mail: zhaojzh@dlut.edu.cn

b School of Environment and Civil Engineering, Dongguan University of Technology, No. 1, Daxue Rd., Songshan Lake, Dongguan, Guangdong Province, P. R. China
E-mail: lichen@mpip-mainz.mpg.de

Abstract

The spin–orbit charge transfer intersystem crossing (SOCT-ISC) of perylenemonoimide–phenothiazine compact dyads was shown to depend on the molecular geometry and the vector dipole orientations of the two chromophores, and the dyads show high triplet state quantum yields (57%).

Graphical abstract: Spin–orbit charge transfer intersystem crossing in perylenemonoimide–phenothiazine compact electron donor–acceptor dyads

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Article information

DOI
https://doi.org/10.1039/C8CC07012A
Article type
Communication
Submitted
29 Aug 2018
Accepted
04 Oct 2018
First published
05 Oct 2018

Chem. Commun., 2018,54, 12329-12332

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Spin–orbit charge transfer intersystem crossing in perylenemonoimide–phenothiazine compact electron donor–acceptor dyads

Y. Zhao, R. Duan, J. Zhao and C. Li, Chem. Commun., 2018, 54, 12329 DOI: 10.1039/C8CC07012A

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