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Issue 87, 2018
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Palladium-catalysed magnesiation of benzene

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Abstract

In the presence of a catalytic quantity of [Pd(PCy3)2], a reagent containing a Mg–Mg bond effects the C–H functionalisation of benzene resulting in a 100% atom efficient transformation to generate an unprecedented aryl magnesium hydride.

Graphical abstract: Palladium-catalysed magnesiation of benzene

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Article information


Submitted
06 Aug 2018
Accepted
08 Oct 2018
First published
08 Oct 2018

Chem. Commun., 2018,54, 12326-12328
Article type
Communication

Palladium-catalysed magnesiation of benzene

M. Garçon, A. J. P. White and M. R. Crimmin, Chem. Commun., 2018, 54, 12326
DOI: 10.1039/C8CC06392C

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