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Issue 99, 2018
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A copper-catalyzed three component reaction of aryl acetylene, sulfonyl azide and enaminone to form iminolactone via 6π electrocyclization

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Abstract

We developed a copper-catalyzed three component reaction of aryl acetylene, enaminone and sulfonyl azide to construct iminolactone via a cascade process involving copper-catalyzed alkyne–azide cycloaddition (CuAAC), Michael addition of metalated ketenimine followed by elimination and 6π electrocyclization.

Graphical abstract: A copper-catalyzed three component reaction of aryl acetylene, sulfonyl azide and enaminone to form iminolactone via 6π electrocyclization

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Publication details

The article was received on 23 Aug 2018, accepted on 19 Nov 2018 and first published on 20 Nov 2018


Article type: Communication
DOI: 10.1039/C8CC06868B
Citation: Chem. Commun., 2018,54, 13953-13956
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    A copper-catalyzed three component reaction of aryl acetylene, sulfonyl azide and enaminone to form iminolactone via 6π electrocyclization

    J. Sun, X. Cheng, J. K. Mansaray, W. Fei, J. Wan and W. Yao, Chem. Commun., 2018, 54, 13953
    DOI: 10.1039/C8CC06868B

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