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Issue 75, 2018
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Electron transfer in a covalent dye–cobalt catalyst assembly – a transient absorption spectroelectrochemistry perspective

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Abstract

Various oxidation states of the catalytically active cobalt center in a covalent dyad were electrochemically prepared and the light-induced excited-state processes were studied. Virtually identical deactivation processes are observed, irrespective of the oxidation state of the cobalt center, varying from CoIII to CoI, indicating the absence of oxidative quenching within the dye–catalyst assembly.

Graphical abstract: Electron transfer in a covalent dye–cobalt catalyst assembly – a transient absorption spectroelectrochemistry perspective

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Publication details

The article was received on 10 Jul 2018, accepted on 09 Aug 2018 and first published on 28 Aug 2018


Article type: Communication
DOI: 10.1039/C8CC05556D
Chem. Commun., 2018,54, 10594-10597

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    Electron transfer in a covalent dye–cobalt catalyst assembly – a transient absorption spectroelectrochemistry perspective

    S. Bold, L. Zedler, Y. Zhang, J. Massin, V. Artero, M. Chavarot-Kerlidou and B. Dietzek, Chem. Commun., 2018, 54, 10594
    DOI: 10.1039/C8CC05556D

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