Palladium-catalyzed sequential three-component reactions to access vinylsilanes

Bo Zhou; Ailan Lu; Changdong Shao; Xinda Liang; Yanghui Zhang

doi:10.1039/C8CC05254A

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Palladium-catalyzed sequential three-component reactions to access vinylsilanes†

Bo Zhou,^a Ailan Lu,^a Changdong Shao,

^a Xinda Liang^a and Yanghui Zhang

*^a

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* Corresponding authors

^a School of Chemical Science and Engineering, Shanghai Key Laboratory of Chemical, Assessment and Sustainability, Tongji University, 1239 Siping Road, Shanghai, P. R. China
E-mail: zhangyanghui@tongji.edu.cn
Web: http://zhangyhgroup.tongji.edu.cn

Abstract

A palladium-catalyzed sequential three-component reaction has been developed. The palladacycles, generated through cascade reactions of aryl halides and alkynes, are the key intermediates and react with hexamethyldisilane to form disilylated products. The reaction represents a useful preparative method for vinylsilanes, and the vinylsilanes can be transformed into tetrasubstituted alkenes.

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DOI: https://doi.org/10.1039/C8CC05254A
Article type: Communication
Submitted: 30 Jun 2018
Accepted: 27 Aug 2018
First published: 28 Aug 2018

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Chem. Commun., 2018,54, 10598-10601

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Palladium-catalyzed sequential three-component reactions to access vinylsilanes

B. Zhou, A. Lu, C. Shao, X. Liang and Y. Zhang, Chem. Commun., 2018, 54, 10598 DOI: 10.1039/C8CC05254A

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Chemical Communications

Palladium-catalyzed sequential three-component reactions to access vinylsilanes†

Abstract

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Palladium-catalyzed sequential three-component reactions to access vinylsilanes

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