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Induced circular dichroism of monoatomic anions: silica-assisted the transfer of chiral environment from molecular assembled nanohelices to halide ions

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Abstract

We demonstrate the first example of induced CD of monoatomic anions. This was detected using chirally-arranged molecular assemblies of non-chiral cationic gemini surfactants (16-2-16) with monoatomic anions stabilized with silica-coating. Furthermore, we have also achieved multi-step transfer of a chiral environment through an in situ chemical reaction via chiralized monoatomic anions.

Graphical abstract: Induced circular dichroism of monoatomic anions: silica-assisted the transfer of chiral environment from molecular assembled nanohelices to halide ions

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Publication details

The article was received on 06 Jul 2018, accepted on 01 Aug 2018 and first published on 01 Aug 2018


Article type: Communication
DOI: 10.1039/C8CC05449E
Citation: Chem. Commun., 2018, Advance Article
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    Induced circular dichroism of monoatomic anions: silica-assisted the transfer of chiral environment from molecular assembled nanohelices to halide ions

    Y. Okazaki, N. Ryu, T. Buffeteau, S. Pathan, S. Nagaoka, E. Pouget, S. Nlate, H. Ihara and R. Oda, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC05449E

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