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Issue 77, 2018
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Towards understanding of lanthanide–transition metal bonding: investigations of the first Ce–Fe bonded complex

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Abstract

The syntheses, structural, and magnetic characterization of three new organometallic Ce complexes stabilized by PyCp22− (PyCp22− = [2,6-(CH2C5H3)2C5H3N]2−) are reported. Complex 1 provides the first example of a crystallographically characterized unsupported Ce–Fe bond in a molecular compound. Results from IR spectroscopy and computational analyses suggest weaker Fe → Ce electron-donation than in a previously reported Dy–Fe bonded species.

Graphical abstract: Towards understanding of lanthanide–transition metal bonding: investigations of the first Ce–Fe bonded complex

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Publication details

The article was received on 02 Jul 2018, accepted on 04 Sep 2018 and first published on 04 Sep 2018


Article type: Communication
DOI: 10.1039/C8CC05243C
Citation: Chem. Commun., 2018,54, 10893-10896

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    Towards understanding of lanthanide–transition metal bonding: investigations of the first Ce–Fe bonded complex

    C. P. Burns, X. Yang, S. Sung, J. D. Wofford, N. S. Bhuvanesh, M. B. Hall and M. Nippe, Chem. Commun., 2018, 54, 10893
    DOI: 10.1039/C8CC05243C

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